\documentclass[reqno]{amsart} \usepackage{graphicx} \usepackage{hyperref} \AtBeginDocument{{\noindent\small {\em Electronic Journal of Differential Equations}, Vol. 2006(2006), No. 149, pp. 1--18.\newline ISSN: 1072-6691. URL: http://ejde.math.txstate.edu or http://ejde.math.unt.edu \newline ftp ejde.math.txstate.edu (login: ftp)} \thanks{\copyright 2006 Texas State University - San Marcos.} \vspace{9mm}} \begin{document} \title[\hfilneg EJDE-2006/149\hfil Nonclassical shock waves] {Nonclassical shock waves of conservation laws: Flux function having two inflection points} \author[H. D. Nghia, M. D. Thanh\hfil EJDE-2006/149\hfilneg] {Ho Dac Nghia, Mai Duc Thanh} % in alphabetical order \address{Ho Dac Nghia \newline Horizon International Bilingual School, 02 Luong Huu hanh, Pham Ngu Lao Ward, District 1, Ho Chi Minh City, Vietnam} \email{dacnghia@yahoo.com} \address{Mai Duc Thanh \newline Department of Mathematics, International University, Quarter 6, Linh Trung Ward, Thu Duc District, Ho Chi Minh City, Vietnam} \email{mdthanh@hcmiu.edu.vn} \thanks{Submitted September 7, 2006. Published December 5, 2006.} \subjclass[2000]{35L65, 76N10, 76L05} \keywords{Conservation law; non-genuine nonlinearity; nonclassical solution; \hfill\break\indent kinetic relation} \begin{abstract} We consider the Riemann problem for non-genuinely nonlinear conservation laws where the flux function admits two inflection points. This is a simplification of van der Waals fluid pressure, which can be seen as a function of the specific volume for a specific entropy at which the system lacks the non-genuine nonlinearity. Corresponding to each inflection point, A nonclassical Riemann solver can be uniquely constructed. Furthermore, two kinetic relations can be used to construct nonclassical Riemann solutions. \end{abstract} \maketitle \numberwithin{equation}{section} \newtheorem{theorem}{Theorem}[section] \newtheorem{lemma}[theorem]{Lemma} \newtheorem{proposition}[theorem]{Proposition} \section{Introduction} The theory of nonclassical solutions of hyperbolic systems of conservation laws has been introduced by LeFloch and has been developed for many years. Nonclassical shocks may appear when the system fails to be genuinely nonlinear. Briefly, nonclassical shock waves violate the standard the Oleinik criterion \cite{Oleinik} in the scalar case and the Lax shock inequalities \cite{Lax71} and the Liu entropy conditions \cite{Liu74} for the case of hyperbolic systems of conservation laws. To select nonclassical shock waves, by a standard way, one follows the strategy proposed by Abeyaratne-Knowles \cite{AbeyaratneKnowles88,AbeyaratneKnowles91}, and by Hayes and LeFloch \cite{HayesLeFloch97, HayesLeFloch00, LeFlochbook} to describe the whole family of {\it nonclassical Riemann solutions} and then to use a {\it kinetic relation} to determine the relevant physical solution. For material on this subject, see the text book \cite{LeFlochbook}. Related works can be found in \cite{LeFloch93, HayesLeFloch97, HayesLeFloch00, LeFlochbook, LeFlochThanh00, LeFlochThanh01, LeFlochThanh02, LeFlochThanh03, James80, Shearer82, Slemrod83, SchulzeShearer, Truskinovsky87, Truskinovsky93, ShearerYang95} and the references therein. In this paper, we consider the Riemann problem for conservation laws, where the flux-function has two inflection points \begin{equation} \begin{gathered} \partial_t u + \partial_x f(u) = 0,\\ u(x,0) = \begin{cases} u_l & \text{for } x < 0, \\ u_r & \text{for } x > 0. \end{cases} \end{gathered} \label{1.1} \end{equation} Here, $u_l$ and $u_r$ are constants. The flux function $f$ is a twice differentiable function of $u\in\mathbb{R}$ and is assumed to satisfy the following hypotheses \begin{equation} \begin{gathered} f''(u) > 0 \quad \text{for } u \in (-\infty,0)\cup (1,+\infty),\\ f''(u) < 0 \quad \text{for } u \in (0,1),\\ \lim_{u \to \pm\infty} f'(u) = +\infty, \quad \lim_{u \to \pm\infty} f(u) = +\infty. \end{gathered}\label{1.2} \end{equation} Thus the flux $f$ has two inflection points at $u=0$ and $u=1$. The specification of these two values does not restrict the scope of consideration of this paper. By assumption, the function $f$ is clearly convex in each interval $(-\infty,0)$ and $(1,+\infty)$, and is concave in the interval $(0,1)$. To specify these intervals, we denote \begin{equation} \begin{gathered} E_I := (-\infty, 0),\\ E_{II} := [0,1],\\ E_{III} := (1,+\infty), \end{gathered} \label{1.3} \end{equation} and call each of them a {\it phase}. In studying nonclassical shocks, one is concerned at the break of the genuine nonlinearity of the system on a manifold. In many situations, this manifold may be reduced to be simply an inflection point of a flux function in appropriate coordinates. In several models such as the Van der Waals fluids, non-genuine nonlinearity may occur not only on one, but on two manifolds of phase domains. In the work of LeFloch-Thanh \cite{LeFlochThanh00}, the presence of two inflection points in the flux function was studied. The nonclassical Riemann solver was constructed by restricting only on the first kinetic function, though we may have several kinetic functions on a Hugoniot curve. More clearly, following the strategy proposed by Abeyaratne-Knowles \cite{AbeyaratneKnowles88,AbeyaratneKnowles91}, and by Hayes-LeFloch \cite{HayesLeFloch97, HayesLeFloch00, LeFlochbook}, the authors define the entropy dissipation to describe the whole set of nonclassical waves. It appears that the entropy dissipation may vanish three times. And this would lead to the definition of two kinetic functions. The domain as well as the range of each of these two kinetic function contains one inflection point and its values are symmetric to the variable values with respect to the inflection point. The difficulty to use the second kinetic function is that the shock speed involving the second kinetic function may be less than that of the shock speed using the first kinetic function. Consequently, the Riemann solution may not be well-defined when two kinetic functions are to be involved. In LeFloch-Thanh \cite{LeFlochThanh03}, phase transitions were observed. All nonclassical shock waves satisfying a single entropy condition that entropy should be nondecreasing in time were also characterized. This paper will deal with the case of two apparent kinetic functions, continuing works in \cite{LeFlochThanh00, LeFlochThanh03}. For simplicity, we restrict our attention to the scalar case where we have a single conservation law. The flux function will have the shape of the pressure of van der Waals fluids in the region where it admits two inflection points. Accordingly, we may have two kinetic functions, and we will consider when we can use each of them, or both. Moreover, as the entropy dissipation selects nonclassical waves like the rule of equal areas, we will define the kinetic functions relying on the rule of equal areas to set up their domains. To select a unique solution, however, we have to restrict the range of kinetic functions such that the chord connecting two states of a nonclassical shock cuts the graph of the flux function at only one point. The construction may be more visual in some sense. We note that a similar way was constructed for classical shock waves by Oleinik \cite{Oleinik}. We note that the existence of nonclassical shock waves is related to the existence of travelling waves of a regularized problem for diffusive-dispersive models, when the diffusive and dispersive coefficients tend to zero, see \cite{LeFlochbook}. This paper is organized as follows. In Section 2 we will investigate the properties of tangents to the graph of $f$, and then we review the Oleinik construction of the entropy solution. Section 3 will be devoted to selecting non-classical Riemann solutions relying on one kinetic relation corresponding to each inflection point. In Section 4 we will give a Riemann solver which involves two kinetic relations. \section{Basic Properties and Oleinik Construction} In this section, first we describe several essential properties of the flux function $f$. Tangents to the graph of $f$ will be used to select nonclassical shocks instead of an entropy dissipation. Second, we review the Oleinik construction for {\it classical entropy solutions} of the problem \eqref{1.1}. Recall that a discontinuity of \eqref{1.1} the form \begin{equation} u(x,t)=\begin{cases} u_l & \text{for } x < st, \\ u_r & \text{for } x > st, \end{cases} \label{2.1} \end{equation} connecting the left-hand state $u_l$ and the right-hand state $u_r$ with shock speed $s$, is called a classical shock of \eqref{1.1} if it satisfies the Rankine-Hugoniot relations \begin{equation} -s(u_r-u_l) + (f(u_r)-f(u_l)) =0, \label{2.2} \end{equation} and the Oleinik entropy criterion \begin{equation} \frac{f(u)-f(u_l)}{u-u_l}\ge\frac{f(u_r)-f(u_l)}{u_r-u_l},\quad \text{for $u$ between $u_r$ and $u_l$}. \label{2.3} \end{equation} The condition \eqref{2.3} means that the graph of $f$ is lying below (above) the line connecting $u_l$ to $u_r$ when $u_r u_l$). \begin{figure}[ht] \begin{center} \includegraphics[width=0.7\textwidth]{fig1} \end{center} %\centerline{\psfig{file=flux.eps,width=8truecm}} \caption{Flux function having two inflection points} \label{Flux} \end{figure} Under the hypotheses \eqref{1.2}, the tangents at $1$ and $0$ cut the graph of the flux function $f$ at points $a$ and $b$, respectively, with $a<0<1d$, the solution is combined from three elementary waves: a rarefaction wave from $u_l$ to $c$, followed by a shock from $c$ to $d$, and then followed by a rarefaction wave from $d$ to $u_r$. Second, we deal with $u_l\in [c,0]$. If $u_r\in (-\infty,u_l)$, the Riemann solution is a single shock. A single rarefaction wave can connect $u_l$ with the states $u_r \in (u_l,0]$. If $u_r\in [0,\phi^{-\natural}(u_l)]$, then ${\phi}^\natural(u_r)\in [u_l,0]$ and the Riemann solution is composed by a rarefaction wave from $u_l$ to ${\phi}^\natural(u_r)$ followed by a shock from ${\phi}^\natural(u_r)$ to $u_r$. A single shock from $u_l$ can reach $u_r\in (\phi^{-\natural}(u_l),{\psi}^\natural(u_l]$. Finally, if $u_r> {\psi}^\natural(u_l)$, the solution is a composite of a shock from $u_l$ to ${\psi}^\natural(u_l)$ followed with a rarefaction wave connecting ${\psi}^\natural(u_l)$ to $u_r$. Third, $u_l\in (0,1)$. A single shock from $u_l$ can reach $u_r\in (-\infty,\phi^{-\natural}(u_l)]\cup [u_l,{\psi}^\natural(u_l)]$. A single rarefaction wave from $u_l$ can connect to $u_r\in [0,u_l]$. If $u_r\in (\phi^{-\natural}(u_l),0)$, then there exists a unique value $u^*\in (0,u_l)$ such that $\phi^{-\natural}(u^*)=u_r$. That is $u^*={\phi}^\natural(u_r)$. In that case the Riemann solution is a rarefaction wave connecting $u_l$ to $u^*$ followed by a shock connecting $u^*$ to $u_r$. Finally, if $u_r> {\psi}^\natural(u_l)$, the Riemann solution is a shock connecting $u_l$ to ${\psi}^\natural(u_l)$ followed with a rarefaction wave from ${\psi}^\natural(u_l)$ to $u_r$. Fourth, assume that $u_l\in [1,b]$. A single shock from $u_l$ can reach $$ u_r\in (-\infty,\phi^{-\natural}({\psi}^\natural(u_l))]\cup [{\psi}^\natural(u_l),u_l]. $$ A single rarefaction wave from $u_l$ can connect to $u_r\in [u_l,+\infty)$. If $u_r\in [0,{\psi}^\natural(u_l))$, the Riemann solution is combined by a shock from $u_l$ to ${\psi}^\natural(u_l)$ followed by a rarefaction from ${\psi}^\natural(u_l)$ to $u_r$. If $u_r\in (\phi^{-\natural}({\psi}^\natural(u_l)),a)$, the solution contained three waves: a shock from $u_l$ to ${\psi}^\natural(u_l)$, followed by a rarefaction from ${\psi}^\natural(u_l)$ to ${\phi}^\natural(u_r)$, and followed by a shock connecting ${\phi}^\natural(u_r)$ to $u_r$. Finally, if $u_l\in (b,+\infty)$, then the Riemann solution is simply a shock if $u_r\phi(u)>{\phi}^\natural(u),\quad\forall u < 0,\\ \phi^{-\natural}(u)<\phi(u)<{\phi}^\natural(u),\quad\forall u > 0,\\ \phi(0)={\phi}^\natural(0)=\phi^{-\natural}(0)=0; \end{gathered} \label{3.1} \end{equation} \item[(A2)] The {\it contraction property} \begin{equation} |\phi \circ \phi (u)| < |u|, \quad\forall u\in \Omega_0, \quad u\ne 0. \label{3.2} \end{equation} \item[(A3)] Conditions at limits: \begin{equation} \phi(p)={\psi}^\natural(p),\quad \phi(1)=a. \label{3.3} \end{equation} \end{itemize} \begin{figure}[ht] \begin{center} \includegraphics[width=0.7\textwidth]{fig2} \end{center} %\centerline{\psfig{file=kinetic_phi.eps,width=8truecm}} \caption{Kinetic Function $\phi$} \label{Kinetic1} %fig 3.1 \end{figure} For an arbitrary non-classical shock between a given left-hand state $u_0$ and a given right-hand state $u_1$, {\it kinetic relation} is the requirement that \begin{equation} u_1=\phi (u_0). \label{3.6} \end{equation} To select non-classical shock rather than classical ones, we postulate that \begin{itemize} \item[(C)] Non-classical shocks are preferred whenever available. \end{itemize} We now solve the Riemann problem relying on this condition . The construction in this section is similar to the non-classical one for the $1$-wave family in \cite{LeFlochThanh00}, but we want to recall it here for completeness. Suppose first that $u_l \in (-\infty,p)$. Any point $u_r \in (-\infty,u_l)$ can be achieved by a single classical shock. Any point $u_r\in (u_l,0]$ is attainable by a single rarefaction wave. If $u_r\in (0,\phi(p)]$, there exists a unique point $u_*\in [p,0)$ such that $u_r=\phi(u_*)$. The solution is then the composite of a rarefaction wave from $u_l$ to $u_*$ followed by a nonclassical shock from $u_*$ to $u_r$. If $u_r\in (\phi(p),+\infty)$, the solution consists of three parts: A rarefaction wave from $u_l$ to $p$ followed by a nonclassical shock from $p$ to $\phi(p)$, followed by a rarefaction wave from $\phi(p)$ to $u_r$. Second, suppose that $u_l\in [p,0)$. A point $u_r\in (-\infty, u_l)$ can be attained by a single classical shock. A point $u_r\in (u_l,0]$ is attainable by a single rarefaction wave. If $u_r\in (0,\phi(u_l)]$, there exists a unique point $u_*\in [u_l,a)$ such that $u_r=\phi(u_*)$. The solution is then the composite of the rarefaction wave from $u_l$ to $u_*$ followed by a nonclassical shock from $u_*$ to $u_r$. If $u_r\in (\phi(u_l),\phi(p)]$, there exists a unique point $u^*\in [p,u_l)$ such that $u_r=\phi(u^*)$. For this construction to make sense, one must here check whether the classical shock from $u_l$ to $u^*$ is slower than the nonclassical shock from $u^*$ to $u_r$. So, consider the function \begin{equation} \tilde f(v) := \begin{cases} f(v),&\text{if } v\in (-\infty, u_l],\\ f(u_l)+f'(u_l)(v-u_l),&\text{if } v \in (u_l,+\infty). \end{cases} \label{3.7} \end{equation} If $u_r\in (\phi(u_l), \eta)$, where $$ \eta:=\min\{\phi(p),\phi^{-\natural}(u_l)\}, $$ the function $\tilde f$ is convex on $(-\infty,+\infty)$ and the points $u^*$ and $u_r$ belong to its epigraph. Therefore, the line segment connecting $u^*$ and $u_r$ should lie above the graph of $\tilde f$ in the interval $(u^*,u_r)\ni u_l$. That is to say $$ {\tilde f(u_l)-\tilde f(u^*)\over u_l-u^*} < {f(u_r)-f(u^*)\over u_r-u^*}, $$ i.e., \begin{equation} s(u_l,u^*)\psi(u)>{\psi}^\natural(u),\quad\forall u < 1,\\ \psi^{-\natural}(u)<\psi(u)<{\psi}^\natural(u),\quad\forall u > 1,\\ \psi(1)={\psi}^\natural(1)=\psi^{-\natural}(1)=1; \end{gathered} \label{3.10} \end{equation} \item[(B2)] The {\it contraction property} \begin{equation} |\psi \circ \psi (u)-1| < |u-1|, \quad\forall u\in \Omega_1,\quad u\ne 1. \label{3.11} \end{equation} \item[(B3)] Conditions at limits: \begin{equation} \psi(q)={\phi}^\natural(q),\quad {\phi}^\natural(\psi(\theta))=\theta. \label{3.12} \end{equation} \end{itemize} \begin{figure}[ht] \begin{center} \includegraphics[width=0.7\textwidth]{fig3} \end{center} %\centerline{\psfig{file=kinetic_psi.eps,width=8truecm}} \caption{Kinetic Function $\psi$} \label{Kinetic2} %fig3.2} \end{figure} For any non-classical shock between a given left-hand state $u_0$ and a given right-hand state $u_1$, kinetic relation for the coming construction is the requirement that \begin{equation} u_1=\psi (u_0). \label{3.15} \end{equation} So, we begin to construct the Riemann solver, postulating the condition (C) in the previous subsection. Assume first that $u_l\in (-\infty,\theta)$. A single classical shock can jump to any $u_r\in (-\infty,u_l)$. A single rarefaction wave can connect $u_l$ from the left to any $u_r\in [u_l,0]$ from the right. If $u_r\in (0,\phi^{-\natural}(\theta)]$, then ${\phi}^\natural(u_r)\in [\theta,0)$, the solution thus is a rarefaction wave from $u_l$ to ${\phi}^\natural(u_r)$ followed by a classical shock from ${\phi}^\natural(u_r$ to $u_r$. If now $u_r\in (\phi^{-\natural}(\theta),\psi(\theta))$, the solution consists of a rarefaction wave from $u_l$ to $\theta$, followed by a non-classical shock from $\theta$ to $\psi(\theta)$, then followed by a classical shock from $\psi(\theta)$ to $u_r$. If $u_r\in [\psi(\theta),+\infty)$, the solution is a composite of a rarefaction wave from $u_l$ to $\theta$, followed by a non-classical shock from $\theta$ to $\psi(\theta)$, then followed by a rareffaction wave from $\psi(\theta)$ to $u_r$. Second, let $u_l\in [\theta,0]$. A single classical shock can jump to any $u_r\in (-\infty,u_l)$. A single rarefaction wave can connect $u_l$ to any $u_r\in [u_l,0]$. If $u_r\in (0,\phi^{-\natural}(u_l)]$, then ${\phi}^\natural(u_r)\in [u_l,0)$, and therefore the solution is a rarefaction wave from $u_l$ to ${\phi}^\natural(u_r)$ followed by a classical shock from ${\phi}^\natural(u_r)$ to $u_r$. If now $u_r\in (\phi^{-\natural}(u_l),\psi^\sharp(u_l,\psi(u_l))]$, the solution is a single classical shock. If $u_r\in (\psi^\sharp(u_l,\psi(u_l)),\psi(u_l))$, then the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $u_r$. If $u_r\in [\psi(u_l),+\infty)$, then the solution is composed from a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $u_r$. Third, let $u_l\in (0,1)$. A single classical shock can arrive at any $u_r\in (-\infty,\newline \phi^{-\natural}(u_l)]$. If $u_r\in (\phi^{-\natural}(u_l),0]$, then ${\phi}^\natural(u_r)\in [0,u_l)$. The solution is thus a rarefaction wave from $u_l$ to ${\phi}^\natural(u_r)$ attached by a classical shock from ${\phi}^\natural(u_r)$ to $u_r$. If $u_r\in (0,u_l]$, the solution is a single rarefaction wave. A single classical shock can arrive at any $u_r\in (u_l,\psi^\sharp(u_l,\psi(u_l))]$. If $u_r\in (\psi^\sharp(u_l,\psi(u_l)),\psi(u_l))$, then the solution is a composite of a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $u_r$. If $u_r\in [\psi(u_l),+\infty)$, then the solution is combined from a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $u_r$. Fourth, assume $u_l\in (1,\psi^{-1}(0))$. By the monotony, we have $$ \psi(u_l)>0. $$ If $u_r\in [u_l,+\infty)$, then the solution is a rarefaction wave. A single classical shock can jump from $u_l$ to any $u_r\in [\psi^\sharp(u_l,\psi(u_l)), u_l)$.\newline If $u_r\in (\psi(u_l),\psi^\sharp(u_l,\psi(u_l)))$, then the solution is combined from two shocks: a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical one from $\psi(u_l)$ to $u_r$. If $u_r\in [0,\psi(u_l)]$, then the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $u_r$. If now $u_r\in (\phi^{-\natural}(\psi(u_l)), 0)$, then ${\phi}^\natural(u_r)\in (0,\psi(u_l))$. The solution is thus a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to ${\phi}^\natural(u_r)$ attached by a classical shock from ${\phi}^\natural(u_r)$ to $u_r$. If $u_r\in [\psi^\sharp(u_l,\psi(u_l)),\phi^{-\natural}(\psi(u_l))]$, then the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $u_r$. If $u_r\in (-\infty,\psi^\sharp(u_l,\psi(u_l)))$, then no non-classical shocks can be involved in the construction. We thus use the classical construction in Section 2 in this interval. The discontinuity in this regime is \begin{equation} u_l\in (1,\psi^{-1}(0)),\quad u_r=\psi^\sharp(u_l,\psi(u_l)). \label{3.16} \end{equation} Fifth, let $u_l\in [\psi^{-1}(0),q]$. The monotony of $\psi$ yields $$ \psi(u_l)\le 0. $$ A single rarefaction wave can connect $u_l$ to any $u_r\in [u_l,+\infty)$. A single classical shock can jump from $u_l$ to any $u_r\in [\psi^\sharp(u_l,\psi(u_l)), u_l)$. If $u_r\in [\phi^{-\natural}(\psi(u_l)),\psi^\sharp(u_l,\psi(u_l)))$, then the solution is combined from two shocks: a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical one from $\psi(u_l)$ to $u_r$. If $u_r\in (0,\phi^{-\natural}(\psi(u_l)))$, then ${\phi}^\natural(u_r)\in (\psi(u_l),0)$. The solution is therefore a composite of a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to ${\phi}^\natural(u_r)$, then attached by a classical shock from ${\phi}^\natural(u_r)$ to $u_r$. If $u_r\in [\psi(u_l),0]$, then the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $u_r$. If $u_r\in [\psi^\sharp(u_l,\psi(u_l)),\psi(u_l))$, then the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical one from $\psi(u_l)$ to $u_r$. If $u_r\in (-\infty,\psi^\sharp(u_l,\psi(u_l)))$, then there are no non-classical shocks and we have a situation similar to the previous one. In this construction, we have a discontinuity sharing the same formula for $u_r$ but $u_l\in [\psi^{-1}(0),q]$ instead. Combining this argument and (3.16), we obtain the curve of discontinuity of the construction \begin{equation} \{u_l\in (1,q],\quad u_r=\psi^\sharp(u_l,\psi(u_l))\}. \label{3.17} \end{equation} Finally, let $u_l\in (q,+\infty)$. In this case we have no non-classical shocks and we use the classical construction as well. The above arguments can be summarized in the following theorem \begin{theorem} \label{thm3.2} Given the initial Riemann data $(u_l,u_r)$. Under the hypotheses \eqref{1.2} and the condition (C), the Riemann problem (1.1) admits a unique self-similar solution made of rarefaction waves, classical shocks and non-classical shocks satisfying the kinetic relation (3.15). The Riemann solver is described by \noindent Case 1: $u_l\in (-\infty,\theta)$. \begin{itemize} \item If $u_r\in (-\infty,u_l)$, the solution is a single classical shock. \item If $u_r\in [u_l,0]$, the solution is a single rarefaction wave. \item If $u_r\in (0,\phi^{-\natural}(\theta)]$, the solution is a rarefaction wave from $u_l$ to ${\phi}^\natural(u_r)$ followed by a classical shock from ${\phi}^\natural(u_r$ to $u_r$. \item If $u_r\in (\phi^{-\natural}(\theta),\psi(\theta))$, the solution is a composite of a rarefaction wave from $u_l$ to $\theta$, followed by a non-classical shock from $\theta$ to $\psi(\theta)$, followed by a classical shock from $\psi(\theta)$ to $u_r$. If $u_r\in [\psi(\theta),+\infty)$, the solution is a rarefaction wave from $u_l$ to $\theta$, followed by a non-classical shock from $\theta$ to $\psi(\theta)$, then followed by a rarefaction wave from $\psi(\theta)$ to $u_r$. \end{itemize} \noindent Case 2: $u_l\in [\theta,0]$. \begin{itemize} \item If $u_r\in (-\infty,u_l)$, then the solution is a classical shock. \item If $u_r\in [u_l,0]$, the solution is a single rarefaction wave. \item If $u_r\in (0,\phi^{-\natural}(u_l)]$, the solution is a rarefaction wave from $u_l$ to ${\phi}^\natural(u_r)$ followed by a classical shock from ${\phi}^\natural(u_r)$ to $u_r$. \item If $u_r\in (\phi^{-\natural}(u_l),\psi^\sharp(u_l,\psi(u_l))]$, the solution is a single classical shock. \item If $u_r\in (\psi^\sharp(u_l,\psi(u_l)),\psi(u_l))$, the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $u_r$. \item If $u_r\in [\psi(u_l),+\infty)$, the solution is a composite of a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $u_r$. \end{itemize} \noindent Case 3: $u_l\in (0,1)$. If $u_r\in (-\infty,\phi^{-\natural}(u_l)]$, the solution is a classical shock. \begin{itemize} \item If $u_r\in (\phi^{-\natural}(u_l),0]$, the solution is a rarefaction wave from $u_l$ to ${\phi}^\natural(u_r)$ attached by a classical shock from ${\phi}^\natural(u_r)$ to $u_r$. \item If $u_r\in (0,u_l]$, the solution is a single rarefaction wave. \item If $u_r\in (u_l,\psi^\sharp(u_l,\psi(u_l))]$, the solution is a single classical shock. \item If $u_r\in (\psi^\sharp(u_l,\psi(u_l)),\psi(u_l))$, the solution is a composite of a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $u_r$. \item If $u_r\in [\psi(u_l),+\infty)$, then the solution is a composite of a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $u_r$. \end{itemize} \noindent Case 4: $u_l\in (1,\psi^{-1}(0))$. \begin{itemize} \item If $u_r\in [u_l,+\infty)$, the solution is a rarefaction wave. \item If $u_r\in [\psi^\sharp(u_l,\psi(u_l)), u_l)$, the solution is a single classical shock. \item If $u_r\in (\psi(u_l),\psi^\sharp(u_l,\psi(u_l)))$, the solution is a composite of two shocks: a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical one from $\psi(u_l)$ to $u_r$. \item If $u_r\in [0,\psi(u_l)]$, the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $u_r$. \item If $u_r\in (\phi^{-\natural}(\psi(u_l)), 0)$, the solution is a composite of a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to ${\phi}^\natural(u_r)$ attached by a classical shock from ${\phi}^\natural(u_r)$ to $u_r$. \item If $u_r\in [\psi^\sharp(u_l,\psi(u_l)),\phi^{-\natural}(\psi(u_l))]$, the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $u_r$. \item If $u_r\in (-\infty,\psi^\sharp(u_l,\psi(u_l)))$, then the construction is classical (Section 2). \end{itemize} \noindent Case 5: $u_l\in [\psi^{-1}(0),q]$. \begin{itemize} \item If $u_r\in [u_l,+\infty)$, the solution is a single rarefaction wave. \item If $u_r\in [\psi^\sharp(u_l,\psi(u_l)), u_l)$, the solution is a single classical shock. \item If $u_r\in [\phi^{-\natural}(\psi(u_l)),\psi^\sharp(u_l,\psi(u_l)))$, the solution is a composite of two shocks: a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical one from $\psi(u_l)$ to $u_r$. \item If $u_r\in (0,\phi^{-\natural}(\psi(u_l)))$, the solution is a composite of three elementary waves: a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to ${\phi}^\natural(u_r)$, then attached by a classical shock from ${\phi}^\natural(u_r)$ to $u_r$. \item If $u_r\in [\psi(u_l),0]$, the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $u_r$. \item If $u_r\in [\psi^\sharp(u_l,\psi(u_l)),\psi(u_l))$, then the solution is a non-classical shock from $u_l$ to $\psi(u_l)$ followed by a classical one from $\psi(u_l)$ to $u_r$. \item If $u_r\in (-\infty,\psi^\sharp(u_l,\psi(u_l)))$, then the construction is classical. \end{itemize} \noindent Case 6: $u_l\in (q,+\infty)$, the construction is classical. The curve of discontinuity is $$ \{u_l\in (1,q],\quad u_r=\psi^\sharp(u_l,\psi(u_l))\}\subset \mathbb{R}^2. $$ \end{theorem} \section{Non-Classical Riemann Solver Using two Kinetic Relations} In this section, we discuss the Riemann solver to the problem \eqref{1.1} using two kinetic relations for non-classical shock-waves between two phases. It turns out that even under the condition (C), non-uniqueness appears. A stronger condition is imposed to guarantee there is a unique choice of non-classical shocks. As expected, the unique Riemann solution does not depend continuously globally on the Riemann data. Let us first point out several circumstances in which there are distinct choices of non-classical solutions adaptable to the condition (C). Firtly, assume that $u_l\in (1,\psi^{-1}(0))$, then $\psi(u_l)\in (0,1)$. Therefore, $$ \phi(\psi(u_l))\in (\phi^{-\natural}(\psi(u_l)),{\phi}^\natural(\psi(u_l)))\subset (\phi^{-\natural}(\psi(u_l)),0). $$ If we take $$ u_r=\phi(\psi(u_l)), $$ then we obtain a solution contains two nonclassical shocks: one nonclassical shock corresponding to the kinetic function $\psi$ from $u_l$ to $\psi(u_l)$, followed by one nonclassical shock corresponding to the kinetic function $\phi$ from $\psi(u_l)$ to $\phi(\psi(u_l))$. However, as derived from the construction in the subsection 3.2 that in this case, we obtained a non-classical solution containing a non-classical shock corresponding to the kinetic function $\psi$: one nonclassical shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $\phi^{-\natural}(u_r)$, attached by a classical shock from $\phi^{-\natural}(u_r)$ to $u_r$. This illustrates the co-existence of two nonclassical solutions, one contains more nonclassical shocks than the other, see Figure 4.1. \begin{figure}[ht] \begin{center} \includegraphics[width=0.7\textwidth]{fig4} \end{center} %\centerline{\psfig{file=double_nshock.eps,width=8truecm}} \caption{Two possible solutions: one contains one and the other contains two nonclassical shocks} \label{two_solution1} %fig4.1 \end{figure} Secondly, assume now $$ u_l\in [\theta, 0],\quad\text{and}\quad u_r\in (\psi^\sharp(u_l,\psi(u_l)),1). $$ According to the description in Section 3, we could have two nonclassical Riemann solutions, each of them contain one nonclassical shock. Precisely, the solution would be \begin{itemize} \item either a classical shock from $u_l$ to $\phi^{-1}(u_r)$, followed by a nonclassical shock corresponding to the kinetic function $\phi$ from $\phi^{-1}(u_r)$ to $u_r$; \item or a nonclassical shock corresponding to the kinetic function $\psi$ from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $u_r$. \end{itemize} This is an example of the co-existence of nonclassical solutions including the same number of nonclassical shocks, see Figure \ref{two_solution2}. \begin{figure}[ht] \begin{center} \includegraphics[width=0.7\textwidth]{fig5} \end{center} %\centerline{\psfig{file=single_nshock.eps,width=8truecm}} \caption{Two distinct solutions: each contains a nonclassical shock} \label{two_solution2} % fig4.2 \end{figure} For short, in the sequel we will name a $0-shock$ (or a $1-shock$) is a nonclasscial shock corresponding to the kinetic function $\phi$ (the kinetic function $\psi$, resp.). In order to select a unique solution, at least we must avoid the above circumstances. In the following, we need a more restrictive procedure than (C). That is the procedure \begin{itemize} \item[(P)] -- A classical solution is understood to contain zero nonclassical shock. -- Nonclassical shocks are preferred whenever available in the extended sense that: If a solver $R_1(u_l,u_r)$ contains $m$ nonclassical shocks, and a solver $R_2(u_l,u_r)$ contains $n$ nonclassical shocks with $m>n$, then $R_1$ excludes $R_2$. -- If the left-hand state belongs to the phase $E_I$, then the $0$-shocks are preferred than the $1$-shocks in the sense that: if $R_1(u_l,u_r)$ and $R_2(u_l,u_r)$ contain the same total number of nonclassical shocks, and $R_1(u_l,u_r)$ contain $m$ $0$-shocks and $R_2(u_l,u_r)$ contain $n$ $0$-shocks with $m>n$, then $R_1$ excludes $R_2$. Similarly, if the left-hand state belongs to the phase $E_{III}$, then $1$-shocks are preferred than the $0$-shocks. \end{itemize} For the construction, we first make it clear that a $1-shock$ can not follow a $0-shock$. \begin{proposition} \label{prop4.1} In any Riemann solution, a $1-shock$ can not follow a $0-shock$. \end{proposition} \begin{proof} Let the states $u_0, u_1, u_2$ be given. Denote $N_0(u_0,u_1)$ is the $0$-shock from $u_0$ to $u_1$ and $N_1(u_1,u_2)$ is the $1$-shock from $u_1$ to $u_2$. That is to say $$ u_1=\phi(u_0),\quad\text{and}\quad u_2=\psi(u_1). $$ In order to for $N_1$ to follow $N_0$ we must have the condition on shock speeds: \begin{equation} s(u_1,u_2)>s(u_0,u_1). \label{4.1} \end{equation} By the definition of kinetic functions, the shock speed $s(u_1,u_2)$ has to be smaller than the slope of the tangent at $u_1$, which is greater than the shock speed $s(u_0,u_1)$. This contradicts with the condition \eqref{4.1}. The proposition is proved. \end{proof} Based on the procedure (P), we proceed now to construct the Riemann solution. First, assume that $u_l\in (-\infty,\min\{\theta, {\phi}^\natural(\phi(p))]$. Since $u_l$ is out of the domain of the kinetic function $\psi$ and, as described in the subsection 3.1, any $u_r\in (0,+\infty)$ can be arrived at by a solution contain one $0$-shock. By virtue of the procedure (P), we thus use the construction in the subsection 3.1 for this interval. Second, let $u_l\in (\min\{\theta, {\phi}^\natural(\phi(p)), 0)$. The construction of the subsection 3.1 is valid for $u_r<\phi^{-\natural}(u_l)$. If $u_r\in [\phi^{-\natural}(u_l),\phi(p)]$, the solution can be a classical shock connecting $u_l$ to $u^*$ followed by a nonclassical shock from $u^*$ to $u_r$ provided \eqref{3.8} holds. If \eqref{3.8} fails, then the construction in the subsection 3.2 can be applied here: if $u_l\le \theta$ we have a rarefaction wave from $u_l$ to $\theta$ followed by a $1$-shock from $\theta$ to $\psi(\theta)$, then followed by a classical shock from $\psi(\theta)$ to $u_r$, if $u_l>\theta$, then we have a $1$-shock from $u_l$ to $\psi(u_l)$ followed by a classical one from $\psi(u_l)$ to $u_r$. For $u_r\in (\phi(p),+\infty)$, if \eqref{3.9} holds then we use the construction in the subsection 3.1 to cover $0$-shocks, else we use the one in the subsection 3.2 to cover $1$-shocks or classical construction. Third, let $u_l\in [0,1]$. We know from Proposition \ref{prop4.1} that $1$-shocks can not follow $0$-shocks, so we need only find the possibility of a $0$-shock following a $1$-shock. The interval $[0,1]$ can be separated by two regions \begin{equation} \begin{gathered} \mathcal{A} := \{u\in [0,1]: \psi^\sharp(u,\psi(u))< 1\}\text{ relatively open in } [0,1],\\ \mathcal{A}^C = [0,1]\setminus \mathcal{A}. \end{gathered} \label{4.2} \end{equation} The relatively open set $\mathcal{A}$ is thus a union of certain relatively open subintervals of the interval $[0,1]$. For any $u\in \mathcal{A}$, there corresponds a set defined by \begin{equation} \mathcal{B }:= \{v \in (a,0): v < \phi(\psi^\sharp(u,\psi(u))),\quad\text{and}\quad v > \phi^\sharp(\psi(u),\phi^{-1}(v))\}. \label{4.3} \end{equation} The set $\mathcal{B}$ is an open subset of $\mathbb{R}$. By definition, given any left-hand state $u_r\in \mathcal{B}$, the Riemann solution for the initial datum $(u_l,u_r)$ is a three-jump wave: first a $1$-shock from $u_l$ to $\psi(u_l)$, followed by a classical jump from $\psi(u_l)$ to $\phi^{-1}(u_r)$, then followed by a $0$-shock from $\phi^{-1}(u_r)$ to $u_r$. For $u_r\in (-\infty,u_l]\setminus \mathcal{B}$, no $1$-shocks to be followed by a $0$-shock, so we use the construction in the subsection 3.1. The states $u_r\in (u_l,+\infty)$ can be reached by the construction in the subsection 3.2, as no $0$-shocks are available. Fourth, assume $u_l\in (1,\psi^{-1}(0)]$. By the monotony, we have \begin{equation} \psi(u_l)> 0. \label{4.4} \end{equation} Due to \eqref{4.4} the right-hand states $u_r\in [0,+\infty)$ should be involved with $1$-shocks and the construction is the one of the subsection 3.2. If $u_r\in (\phi(\psi(u_l)),0)$, then the solution is a $1$-shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $\phi^{-1}(u_r)$, then followed by a $0$-shock from $\phi^{-1}(u_r)$ to $u_r$. If $u_r\in (\phi^\sharp(u_l,\psi(u_l)),\newline \phi(\psi(u_l))]$, then $\phi^{-1}(u_r)\in (\psi(u_l),1)$. The solution is a $1$-shock from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $\phi^{-1}(u_r)$, then followed by a $0$-shock from $\phi^{-1}(u_r)$ to $u_r$ iff \begin{equation} s(\psi(u_l),\phi^{-1}(u_r)) < s(\phi^{-1}(u_r),u_r). \label{4.5} \end{equation} If \eqref{4.5} fails, then no $0$-shocks are involved in the construction and we use the one in the subsection 3.2. If now $u_r\in (-\infty, \phi^\sharp(u_l,\psi(u_l))]$, then the classical construction is invoked. Fifth, let $u_l\in (\psi^{-1}(0),q]$, then \begin{equation} \psi(u_l)< 0. \label{4.6} \end{equation} The right-hand states $u_r\in [\psi^\sharp(u_l,\psi(u_l)),+\infty)\cup (-\infty,0]$ can be arrived at as in the construction of the subsection 3.2. If $u_r\in (0,\phi(\psi(u_l)))$, then the solution is a $1$-shock from $u_l$ to $\psi(u_l)$ followed by a rarefaction wave from $\psi(u_l)$ to $\phi^{-1}(u_r)$ by virtue of (4.6), then followed by a $0$-shock from $\phi^{-1}(u_r)$ to $u_r$. If $u_r\in [\phi(\psi(u_l)),\psi^\sharp(u_l,\psi(u_l)))$, then $\phi^{-1}(u_r)\in (p,\psi(u_l))$. The solution is a $1$-shock from $u_l$ to $\psi(u_l)$ followed by a classical shock from $\psi(u_l)$ to $\phi^{-1}(u_r)$, then followed by a $0$-shock from $\phi^{-1}(u_r)$ to $u_r$ if and only if \begin{equation} s(\psi(u_l),\phi^{-1}(u_r)) < s(\phi^{-1}(u_r),u_r). \label{4.7} \end{equation} If \eqref{4.7} fails, then we use the one in the subsection 3.2. Finally, if $u_l\in (q,+\infty)$, then the classical construction is valid. Summarizing the above arguments, we arrive at the following theorem. \begin{theorem} \label{thm4.2} Given the initial Riemann data $(u_l,u_r)$. 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